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Since the Montreal Protocol on Substances that Deplete the Ozone Layer and its amendments came into effect, growth rates of the major ozone depleting substances (ODS), particularly CFC-11, -12 and -113 and CH3CCl3, have declined markedly, paving the way for global stratospheric ozone recovery. Emissions have now fallen to relatively low levels, therefore the rate at which this recovery occurs will depend largely on the atmospheric lifetime of these compounds. The first ODS measurements began in the early 1970s along with the first lifetime estimates calculated by considering their atmospheric trends. We now have global mole fraction records spanning multiple decades, prompting this lifetime re-evaluation. Using surface measurements from the Advanced Global Atmospheric Gases Experiment (AGAGE) and the National Oceanic and Atmospheric Administration Global Monitoring Division (NOAA GMD) from 1978 to 2011, we estimated the lifetime of CFC- 11, CFC-12, CFC-113 and CH3CCl3 using a multi-species inverse method. A steady-state lifetime of 45 yr for CFC- 11, currently recommended in the most recent World Meteorological Organisation (WMO) Scientific Assessments of Ozone Depletion, lies towards the lower uncertainty bound of our estimates, which are 54 61/48 yr (1-sigma uncertainty) when AGAGE data were used and 52 61/45 yr when the NOAA network data were used. Our derived lifetime for CFC-113 is significantly higher than the WMO estimates of 85 yr, being 109 121/99 (AGAGE) and 109 124/97 (NOAA). New estimates of the steady-state lifetimes of CFC-12 and CH3CCl3 are consistent with the current WMO recommendations, being 111 132/95 and 112 136/95 yr (CFC-12, AGAGE and NOAA respectively) and 5.045.20 4.92 and 5.04 5.23/4.87 yr (CH3CCl3, AGAGE and NOAA respectively).

© 2013 the authors

Atmospheric measurements show that emissions of hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs) are now the primary drivers of the positive growth in synthetic greenhouse gas (SGHG) radiative forcing. We infer recent SGHG emissions and examine the impact of future emissions scenarios, with a particular focus on proposals to reduce HFC use under the Montreal Protocol. If these proposals are implemented, overall SGHG radiative forcing could peak at around 355 mW m-2 in 2020, before declining by approximately 26% by 2050, despite continued growth of fully fluorinated greenhouse gas emissions. Compared to “no HFC policy” projections, this amounts to a reduction in radiative forcing of between 50 and 240 mW m-2 by 2050, or a cumulative emissions saving equivalent to 0.5 to 2.8 years of CO2 emissions at current levels. However, more complete reporting of global HFC emissions is required, as less than half of global emissions are currently accounted for.

© 2014 American Geophysical Union

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National Ambient Air Quality Standards (NAAQS) have been established for each. As of 2013, over 100 million people in the U.S. lived in areas with ozone concentrations above the NAAQS.

NOx emissions from the power sector, roughly 12% of total NOx emissions, are and will be significant contributors to ozone concentrations in the U.S. As such, states have reduced peak ozone concentrations through technology-based standards and cap-and-trade programs on NOx emissions from the power sector. These policies have largely treated NOx emissions uniformly. But marginal damages from NOx emissions are greatest on hot sunny days when meteorological conditions favor high ozone formation rates and, consequently, peak ozone concentrations.

This thesis informs what type of policy is the most efficient for reducing peak ozone concentrations on high ozone days by assessing the cost-effectiveness of three policies for reducing NOx emissions on high ozone days. Emissions and costs under a relatively-novel differentiated policy, time-differentiated pricing, are compared for the first time to two currently-implemented undifferentiated policies, cap-and-trade and technology-based standards. Two power systems are studied, Texas and the Mid-Atlantic. A unique two-phase model is developed to capture the short- (redispatching) and long-term (control technology installation) effects of pricing schemes on power plants. The two-phase model dispatches generators with a unit commitment model, which, unlike past studies, captures real-world operational constraints of generators that may strongly influence emissions and costs under time-differentiated pricing. Technology-based standards are simulated via Monte Carlo analysis to capture the uncertain rulemaking process.

For reducing NOx emissions on high ozone days in both power systems, time-differentiated pricing is shown to be the most cost-effective policy with regards to producer and consumer costs. Most emissions reductions are due to substitution of gas- for coal-fired generators, as control technology installations are only observed at very high time-differentiated prices. For reducing summer-wide NOx emissions, undifferentiated pricing is the most cost-effective. In a minority of allocations, technology-based standards also achieve more cost-effective summer-wide reductions than time-differentiated pricing, but such allocations cannot be guaranteed ex ante. These results suggest that time-differentiated pricing is the most efficient policy for reducing peak ozone concentrations, depending on ozone formation rates.

China leads the world in installed wind capacity, which forms an integral part of its long-term goals to reduce the environmental impacts of the electricity sector. This primarily centrally-managed wind policy has concentrated wind development in a handful of regions, challenging regulatory frameworks and grid architectures to cost-effectively integrate wind. In 2013, according to official statistics, wind accounted for 2.7% of national generation, while the rate of curtailment (available wind not accepted by the grid operator onto the system) reached 12%.

Wind integration challenges have arisen in China for technical, economic and institutional reasons. From a technology standpoint, the variability and unpredictability of wind resources interact with technical limits of conventional generators, resulting in efficiency losses and grid stability concerns. Existing coal-based electricity and district heating installations play a large role in grid integration challenges because of the inflexible operation of coal plants relative to natural gas and hydropower, and the “must-run” nature of cogeneration units supplying residential heat. A competing set of hypotheses to explain current rates of wind spillage focus on institutional imperfections in China’s power sector, such as poorly designed market incentives, inadequate oversight, and a mixture of conflicting policies that are the result of an incomplete transition to a market-driven electricity system.

A unit commitment and dispatch optimization was developed to understand the underlying technical factors leading to wind curtailment in northeastern China. It incorporates electricity output restrictions from exogenous district heating demands, a hydro-thermal coordination component considering inter-seasonal storage, and transmission between adjacent provincial nodes. Averaging over six historic wind profiles, a curtailment rate of 6.6% was observed in the reference case from various forms of inflexibility and insufficient demand. The impacts of several technology-based solutions on total cost, coal use and wind curtailment, were also examined: more flexible operation of coal units, temporary heat storage and minimum cogeneration outputs that vary with heat load.

Contributing to the existing body of qualitative work on the effects of these factors, this thesis developed a straightforward methodology to assess the relative contribution of regulatory and technical causes. Two important institutional arrangements – the decentralization of dispatch to individual provinces and minimum generation quotas allocated to all coal generators – were quantified in an optimization framework, and found to be significant contributors of power system operational inflexibility.

Passenger vehicles and power plants are major sources of greenhouse gas emissions. While economic analyses generally indicate that a broader market-based approach to greenhouse gas reduction would be less costly and more effective, regulatory approaches have found greater political success. Vehicle efficiency standards have a long history in the U.S and elsewhere, and the recent success of shale gas in the U.S. leads to a focus on coal–gas fuel switching as a way to reduce power sector emissions. We evaluate a global regulatory regime that replaces coal with natural gas in the electricity sector and imposes technically achievable improvements in the efficiency of personal transport vehicles. Its performance and cost are compared with other scenarios of future policy development including a no policy world, achievements under the Copenhagen accord, and a price-based policy to reduce global emissions by 50% by 2050. The assumed regulations applied globally achieve a global emissions reduction larger than projected for the Copenhagen agreements, but they do not prevent global GHG emissions from continuing to grow, and the reduction in emissions is achieved at a high cost compared to a price-based policy. Diagnosis of the reasons for the limited yet high-cost performance reveals influences including the partial coverage of emitting sectors, small or no influence on the demand for emissions-intensive products, leakage when a reduction in fossil use in the covered sectors lowers the price to others, and the partial coverage of GHGs.

We develop a water resource system model of the US (WRS-US) that identifies 99 river basins. The model is built on river basin-specific estimates of water requirements for thermoelectric cooling, irrigation, public supply, self-supply and mining. WRS-US allocates water resources across uses in order to minimize water stress over the year in each river basin. We use the model to predict water stress through to 2050 under two climate policies and two climate models. The largest water stresses are predicted to occur in the South West of the US. Average water stress is not expected to be alleviated by a constrained GHG emission policy by 2050. However, the mitigation policy will reduce inter-annual variability of water stress.

Adequate quantification of evapotranspiration (ET) is crucial to assess how climate change and land cover change (LCC) interactwith the hydrological cycle of terrestrial ecosystems. The Mongolian Plateau plays a unique role in the global climate system due to its ecological vulnerability, high sensitivity to climate change and disturbances, and limited water resources. Here, we used a version of the Terrestrial Ecosystem Model that has been modified to use Penman–Monteith (PM) based algorithms to calculate ET. Comparison of site-level ET estimates from the modified model with ET measured at eddy covariance (EC) sites showed better agreement than ET estimates from the MODIS ET product, which overestimates ET during the winter months. The modified model was then used to simulate ET during the 21st century under six climate change scenarios by excluding/including climate-induced LCC. We found that regional annual ET varies from 188 to 286 mm yr−1 across all scenarios, and that it increases between 0.11 mm yr−2 and 0.55 mm yr−2 during the 21st century. A spatial gradient of ET that increases fromthe southwest to the northeast is consistent in all scenarios. Regional ET in grasslands, boreal forests and semi-desert/deserts ranges from 242 to 374 mm yr−1, 213 to 278 mm yr−1 and 100 to 199 mm yr−1, respectively; and the degree of the ET increase follows the order of grassland, semi-desert/desert, and boreal forest. Across the plateau, climate-induced LCC does not lead to a substantial change (b5%) in ET relative to a static land cover, suggesting that climate change ismore important than LCC in determining regional ET. Furthermore, the differences between precipitation and ET suggest that the available water for human use (water availability) on the plateau will not change significantly during the 21st century. However, more water is available and less area is threatened by water shortage in the Business-As-Usual emission scenarios relative to level-one stabilization emission scenarios.

© 2013 Elsevier B.V.

Soil consumption of atmospheric methane plays an important secondary role in regulating the atmospheric CH4 budget, next to the dominant loss mechanism involving reaction with the hydroxyl radical (OH). Here we used a process-based biogeochemistry model to quantify soil consumption during the 20th and 21st centuries. We estimated that global soils consumed 32–36 Tg CH4 yr−1 during the 1990s. Natural ecosystems accounted for 84% of the total consumption, and agricultural ecosystems only consumed 5 Tg CH4 yr−1 in our estimations. During the twentieth century, the consumption rates increased at 0.03–0.20 Tg CH4 yr−2 with seasonal amplitudes increasing from 1.44 to 3.13 Tg CH4 month−1. Deserts, shrublands, and xeric woodlands were the largest sinks. Atmospheric CH4 concentrations and soil moisture exerted significant effects on the soil consumption while nitrogen deposition had a moderate effect. During the 21st century, the consumption is predicted to increase at 0.05-1.0 Tg CH4 yr−2, and total consumption will reach 45–140 Tg CH4 yr−1 at the end of the 2090s, varying under different future climate scenarios. Dry areas will persist as sinks, boreal ecosystems will become stronger sinks, mainly due to increasing soil temperatures. Nitrogen deposition will modestly reduce the future sink strength at the global scale. When we incorporated the estimated global soil consumption into our chemical transport model simulations, we found that nitrogen deposition suppressed the total methane sink by 26 Tg during the period 1998–2004, resulting in 6.6 ppb higher atmospheric CH4 mixing ratios compared to without considering nitrogen deposition effects. On average, a cumulative increase of every 1 Tg soil CH4 consumption decreased atmospheric CH4 mixing ratios by 0.26 ppb during the period 1998–2004.

© 2013 American Geophysical Union

We used a biogeochemistry model, the Terrestrial Ecosystem Model (TEM), to examine the methane (CH4) exchanges between terrestrial ecosystems and the atmosphere in Northern Eurasia from 1971 to 2100. Multiple model simulations using various wetland extent datasets and climate change scenarios were conducted to assess the uncertainty of CH4 fluxes, including emissions and consumption. On the basis of these simulations we estimate the current net emissions in the region to be 20–24 Tg CH4 yr − 1 (1 Tg = 1012 g), two-thirds of which are emitted during the summer. In response to climate change over the 21st century, the annual CH4 emissions in the region are projected to increase at a rate of 0.06 Tg CH4 yr − 1, which is an order of magnitude greater than that of annual CH4 consumption. Further, the annual net CH4 emissions are projected to increase by 6–51% under various wetland extent datasets and climate scenarios by the end of the 21st century, relative to present conditions. Spatial patterns of net CH4 emissions were determined by wetland extent. Net CH4 emissions were dominated by wetlands within boreal forests, grasslands and wet tundra areas in the region. Correlation analyses indicated that water table depth and soil temperature were the two most important environmental controls on both CH4 emissions and consumption in the region. Our uncertainty analyses indicated that the uncertainty in wetland extent had a larger effect on future CH4 emissions than the uncertainty in future climate. This study suggests that better characterization of the spatial distribution and the natural diversity of wetlands should be a research priority for quantifying CH4 fluxes in this region.

© 2011 IOP Publishing Ltd.
 

This thesis explores the potential risk implications that a large penetration of intermittent renewable electricity generation -- such as wind and solar power -- may have on the future electricity generation technology mix, focusing on the anticipated new operating conditions of different thermal generating technologies and their remuneration in a competitive market environment. In addition, this thesis illustrates with an example how risk should be valued at the power plant level in order to internalize the potential risks to which the generators are exposed.

This thesis first compares the impacts of three different bidding rules on wholesale prices and on the remuneration of units in power systems with a significant share of renewable generation. The effects of bidding rules are distinguished from the effects of regulatory uncertainty that can unexpectedly increase renewable generation by considering two distinct situations: 1) an 'adapted' capacity mix, which is optimized for any given amount of renewable penetration, and 2) a 'non-adapted' capacity mix, which is optimized for zero renewable penetration, but that operates with a certain non-zero renewable capacity, added on top of an already adequate system. The analysis performed stresses the importance of sound mechanisms that allow the full-cost recovery of plants in a system where the intermittency of renewables accentuates nonconvex costs, without over-increasing the cost paid by consumers for electricity. Additionally, the analysis quantifies the potential losses incurred by different thermal technologies if renewable deployment occurs without allowing for adaptation.

Methodologically, this thesis uses a novel long-term generation investment model, the Investment Model for Renewable Electricity Systems (IMRES), to determine the minimum cost thermal capacity mix necessary to complement renewable generation to meet electricity demand, and to extract hourly wholesale prices. IMRES is a capacity expansion model with unit commitment constraints whose main characteristics are: 1) reflecting the impact of hourly resolution operation constraints on investment decisions and on total generation cost; 2) accounting for the chronological variability of demand and renewable output, and the correlation between the two; and 3) deciding on power plant investments at the individual 5 plant level. These characteristics allow for a detailed analysis of the profits obtained by individual plants in systems with large renewable penetration levels. In addition, this thesis tests the performance of a heuristic method that selects four weeks from a full year series to optimally represent the net load duration curve (i.e., the difference between demand and renewable output, decreasingly ordered). For each application of this heuristic method, three metrics are proposed to reflect that the approximation also represents the chronological variability of the net load.

Lastly, this thesis explores the role of risk in the valuation of electricity generating technologies and shows how to incorporate standard risk pricing principles into the popular Monte Carlo simulation analysis. The exposition is structured using the standard framework for a typical Monte Carlo cash flow simulation so that the implementation can be readily generalized. This framework stresses the necessity of an asset pricing approach to assess the relationship between the risk in the assets cash flows and the macroeconomic risk with which the financial investors are concerned. The framework provided is flexible and can accommodate many different structures for the interaction between the macroeconomic risk and the risks in the asset's cash flows (such as those from shocks in renewable deployment).

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